Condensed-phase molecular spectroscopy and photophysics / Anne Myers Kelley, University of California, Merced, USA.

By: Kelley, Anne Myers, 1958- [author.]
Language: English Publisher: Hoboken, NJ : John Wiley & Sons, Inc., 2022Edition: Second editionDescription: 1 online resourceContent type: text Media type: computer Carrier type: online resourceISBN: 9781119829263 ; 9781119829287; 1119829283; 9781119829270; 1119829275Subject(s): Condensed matter -- Spectra | Molecular spectroscopy | Quantum theory | Semiconductors -- SpectraGenre/Form: Electronic books.DDC classification: 543/.54 LOC classification: QC173.458.S64Online resources: Full text is available at Wiley Online Library Click here to view.
Contents:
Table of Contents Preface to Second Edition Preface to First Edition About the Companion Website I. BACKGROUND 1. Time-Independent Quantum Mechanics 1.1. states, operators, and representations 1.2. eigenvalue problems and the Schrödinger equation 1.3. expectation values, uncertainty relations 1.4. particle in a box 1.5. harmonic oscillator 1.6. the rigid rotator and angular momentum 1.7. the hydrogen atom 1.8. approximation methods 1.9. electron spin 1.10. Born-Oppenheimer approximation 1.11. molecular orbitals 1.12. energies and time scales, separation of motions 2. Classical Description of Electromagnetic Radiation 2.1. Maxwell’s equations, plane waves, electric and magnetic fields, polarization 2.2. Fourier transform relationships between time and frequency 2.3. blackbody radiation 2.4. light sources for spectroscopy 3. Statistical mechanics 3.1. the partition function 3.2. the Boltzmann distribution 4. Group theory 4.1. qualitative aspects of molecular symmetry 4.2. introductory group theory 4.3. finding the symmetries of vibrational modes of a certain type 4.4. finding the symmetries of all vibrational modes II. FUNDAMENTALS OF SPECTROSCOPY 5. Radiation-Matter Interactions 5.1. the time-dependent Schrödinger equation 5.2. time-dependent perturbation theory 5.3. interaction of matter with the classical radiation field 5.4. quantum mechanical description of radiation 5.5. interaction of matter with the quantized radiation field 6. Absorption and Emission of Light by Matter 6.1. Einstein coefficients for absorption and emission 6.2. other measures of absorption strength (absorption cross-section, Beer-Lambert Law) 6.3. radiative lifetimes 6.4. oscillator strengths 6.5. local fields 7. System-Bath Interactions 7.1. phenomenological treatment of relaxation and lineshapes 7.2. the density matrix 7.3. density matrix methods in spectroscopy 7.4. exact density matrix solution for a 2-level system 8. Atomic Spectroscopy 8.1. electron configurations 8.2. addition of angular momenta 8.3. term symbols 8.4. angular momentum coupling schemes 8.5. spin-orbit coupling 8.6. energies and selection rules 8.7. Zeeman effect 8.8. hyperfine splitting 9. Rotational Spectroscopy 9.1. rotational transitions of diatomic molecules 9.2. rotational spectroscopy of polyatomic molecules—symmetric, near-symmetric, and asymmetric tops 10. Molecular Vibrations and Infrared Spectroscopy 10.1. vibrational and rovibrational transitions 10.2. diatomic vibrations 10.3. anharmonicity 10.4. polyatomic molecular vibrations; normal modes 10.5. vibration-rotation interactions 10.6. symmetry considerations 10.7. isotopic shifts 10.8. solvent effects on vibrational spectra 11. Electronic Spectroscopy 11.1. electronic transitions 11.2. spin and orbital selection rules 11.3. vibronic structure 11.4. vibronic coupling 11.5. the Jahn-Teller effect 11.6. considerations in large molecules 11.7. solvent effects on electronic spectra 12. Photophysical Processes 12.1. Jablonski diagrams 12.2. quantum yields and lifetimes 12.3. Fermi’s Golden Rule for radiationless transitions 12.4. internal conversion and intersystem crossing 12.5. bright state-dark state coupling and intramolecular vibrational relaxation 12.6. energy transfer 12.7. polarization and molecular reorientation in solution 13. Light Scattering 13.1. Rayleigh scattering from particles 13.2. classical treatment of molecular Raman and Rayleigh scattering 13.3. quantum mechanical treatment of molecular Raman and Rayleigh scattering 13.4. nonresonant Raman scattering 13.5. symmetry considerations and depolarization ratios in Raman scattering 13.6. resonance Raman spectroscopy III. ADVANCED AND SPECIALIZED TOPICS IN SPECTROSCOPY 14. Nonlinear and Pump-Probe Spectroscopies 14.1. linear and nonlinear susceptibilities 14.2. multiphoton absorption 14.3. pump-probe spectroscopy: transient absorption and stimulated emission 14.4. vibrational oscillations and impulsive stimulated scattering 14.5. second harmonic and sum frequency generation 14.6. four-wave mixing 14.7. photon echoes 14.8. hyper-Raman scattering 14.9. broadband stimulated Raman scattering 15. Two-dimensional spectroscopies 15.1. the basics of two-dimensional spectroscopy 15.2. Fourier transform spectroscopy 15.3. implementation of Fourier transform 2D spectroscopy 16. Electron Transfer Processes 16.1. charge-transfer transitions 16.2. Marcus theory 16.3. spectroscopy of anions and cations 17. Collections of Molecules 17.1. van der Waals molecules 17.2. dimers and aggregates 17.3. localized and delocalized excited states 17.4. conjugated polymers 18. Metals and Plasmons 18.1. dielectric function of a metal 18.2. plasmons 18.3. spectroscopy of metal nanoparticles 18.4. surface-enhanced Raman and fluorescence 19. Crystals 19.1. crystal lattices 19.2. phonons in crystals 19.3. infrared and Raman spectra 19.4. phonons in nanocrystals 20. Electronic Spectroscopy of Semiconductors 20.1. band structure 20.2. direct and indirect transitions 20.3. excitons 20.4. defects 20.5. semiconductor nanocrystals 21. Single-molecule spectroscopy 21.1. detection of single-molecule signals 21.2. verification of single-molecule signals 21.3. frequency selection 21.4. spatial selection using far-field optics 21.5. spatial selection using near-field optics 21.6. what is learned from studying one molecule at a time? 22. Time-domain treatment of steady-state spectroscopies 22.1. time correlation function approach to IR and Raman lineshapes 22.2. time-dependent wavepacket picture of electronic spectroscopy 22.3. time-dependent wavepacket picture of resonance Raman intensities APPENDICES A. Physical constants, unit systems and conversion factors B. Miscellaneous mathematics review C. Matrices and determinants D. Character tables for point groups E. Fourier transforms Index
Summary: "This book comprehensively covers radiation-matter interactions for molecules in condensed phases along with metallic and semiconductor nanostructures. Organized and appropriate for both researchers and advanced students, the text differs from others through its emphasis on the molecule-environment interactions that strongly influence spectra in condensed phases alongside including spectroscopy and photophysics of molecular aggregates and molecular solids and of metals and semiconductors, as well as more modern topics such as two-dimensional and single-molecule spectroscopy. In this new 2nd edition, the author adds basic rotational spectroscopy and statistical mechanics; sections on some Raman scattering, two-dimensional spectroscopies, and single-molecule spectroscopies; and a chapter on time-domain pictures of steady-state spectroscopies"-- Provided by publisher.
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Includes bibliographical references and index.

Table of Contents

Preface to Second Edition

Preface to First Edition

About the Companion Website

I. BACKGROUND

1. Time-Independent Quantum Mechanics

1.1. states, operators, and representations

1.2. eigenvalue problems and the Schrödinger equation

1.3. expectation values, uncertainty relations

1.4. particle in a box

1.5. harmonic oscillator

1.6. the rigid rotator and angular momentum

1.7. the hydrogen atom

1.8. approximation methods

1.9. electron spin

1.10. Born-Oppenheimer approximation

1.11. molecular orbitals

1.12. energies and time scales, separation of motions

2. Classical Description of Electromagnetic Radiation

2.1. Maxwell’s equations, plane waves, electric and magnetic fields, polarization

2.2. Fourier transform relationships between time and frequency

2.3. blackbody radiation

2.4. light sources for spectroscopy

3. Statistical mechanics

3.1. the partition function

3.2. the Boltzmann distribution

4. Group theory

4.1. qualitative aspects of molecular symmetry

4.2. introductory group theory

4.3. finding the symmetries of vibrational modes of a certain type

4.4. finding the symmetries of all vibrational modes

II. FUNDAMENTALS OF SPECTROSCOPY

5. Radiation-Matter Interactions

5.1. the time-dependent Schrödinger equation

5.2. time-dependent perturbation theory

5.3. interaction of matter with the classical radiation field

5.4. quantum mechanical description of radiation

5.5. interaction of matter with the quantized radiation field

6. Absorption and Emission of Light by Matter

6.1. Einstein coefficients for absorption and emission

6.2. other measures of absorption strength (absorption cross-section, Beer-Lambert Law)

6.3. radiative lifetimes

6.4. oscillator strengths

6.5. local fields

7. System-Bath Interactions

7.1. phenomenological treatment of relaxation and lineshapes

7.2. the density matrix

7.3. density matrix methods in spectroscopy

7.4. exact density matrix solution for a 2-level system

8. Atomic Spectroscopy

8.1. electron configurations

8.2. addition of angular momenta

8.3. term symbols

8.4. angular momentum coupling schemes

8.5. spin-orbit coupling

8.6. energies and selection rules

8.7. Zeeman effect

8.8. hyperfine splitting

9. Rotational Spectroscopy

9.1. rotational transitions of diatomic molecules

9.2. rotational spectroscopy of polyatomic molecules—symmetric, near-symmetric, and asymmetric tops

10. Molecular Vibrations and Infrared Spectroscopy

10.1. vibrational and rovibrational transitions

10.2. diatomic vibrations

10.3. anharmonicity

10.4. polyatomic molecular vibrations; normal modes

10.5. vibration-rotation interactions

10.6. symmetry considerations

10.7. isotopic shifts

10.8. solvent effects on vibrational spectra

11. Electronic Spectroscopy

11.1. electronic transitions

11.2. spin and orbital selection rules

11.3. vibronic structure

11.4. vibronic coupling

11.5. the Jahn-Teller effect

11.6. considerations in large molecules

11.7. solvent effects on electronic spectra

12. Photophysical Processes

12.1. Jablonski diagrams

12.2. quantum yields and lifetimes

12.3. Fermi’s Golden Rule for radiationless transitions

12.4. internal conversion and intersystem crossing

12.5. bright state-dark state coupling and intramolecular vibrational relaxation

12.6. energy transfer

12.7. polarization and molecular reorientation in solution

13. Light Scattering

13.1. Rayleigh scattering from particles

13.2. classical treatment of molecular Raman and Rayleigh scattering

13.3. quantum mechanical treatment of molecular Raman and Rayleigh scattering

13.4. nonresonant Raman scattering

13.5. symmetry considerations and depolarization ratios in Raman scattering

13.6. resonance Raman spectroscopy

III. ADVANCED AND SPECIALIZED TOPICS IN SPECTROSCOPY

14. Nonlinear and Pump-Probe Spectroscopies

14.1. linear and nonlinear susceptibilities

14.2. multiphoton absorption

14.3. pump-probe spectroscopy: transient absorption and stimulated emission

14.4. vibrational oscillations and impulsive stimulated scattering

14.5. second harmonic and sum frequency generation

14.6. four-wave mixing

14.7. photon echoes

14.8. hyper-Raman scattering

14.9. broadband stimulated Raman scattering

15. Two-dimensional spectroscopies

15.1. the basics of two-dimensional spectroscopy

15.2. Fourier transform spectroscopy

15.3. implementation of Fourier transform 2D spectroscopy

16. Electron Transfer Processes

16.1. charge-transfer transitions

16.2. Marcus theory

16.3. spectroscopy of anions and cations

17. Collections of Molecules

17.1. van der Waals molecules

17.2. dimers and aggregates

17.3. localized and delocalized excited states

17.4. conjugated polymers

18. Metals and Plasmons

18.1. dielectric function of a metal

18.2. plasmons

18.3. spectroscopy of metal nanoparticles

18.4. surface-enhanced Raman and fluorescence

19. Crystals

19.1. crystal lattices

19.2. phonons in crystals

19.3. infrared and Raman spectra

19.4. phonons in nanocrystals

20. Electronic Spectroscopy of Semiconductors

20.1. band structure

20.2. direct and indirect transitions

20.3. excitons

20.4. defects

20.5. semiconductor nanocrystals

21. Single-molecule spectroscopy

21.1. detection of single-molecule signals

21.2. verification of single-molecule signals

21.3. frequency selection

21.4. spatial selection using far-field optics

21.5. spatial selection using near-field optics

21.6. what is learned from studying one molecule at a time?

22. Time-domain treatment of steady-state spectroscopies

22.1. time correlation function approach to IR and Raman lineshapes

22.2. time-dependent wavepacket picture of electronic spectroscopy

22.3. time-dependent wavepacket picture of resonance Raman intensities

APPENDICES

A. Physical constants, unit systems and conversion factors

B. Miscellaneous mathematics review

C. Matrices and determinants

D. Character tables for point groups

E. Fourier transforms

Index

"This book comprehensively covers radiation-matter interactions for molecules in condensed phases along with metallic and semiconductor nanostructures. Organized and appropriate for both researchers and advanced students, the text differs from others through its emphasis on the molecule-environment interactions that strongly influence spectra in condensed phases alongside including spectroscopy and photophysics of molecular aggregates and molecular solids and of metals and semiconductors, as well as more modern topics such as two-dimensional and single-molecule spectroscopy. In this new 2nd edition, the author adds basic rotational spectroscopy and statistical mechanics; sections on some Raman scattering, two-dimensional spectroscopies, and single-molecule spectroscopies; and a chapter on time-domain pictures of steady-state spectroscopies"-- Provided by publisher.

About the Author

Anne Myers Kelley, PhD is a founding faculty of the Department of Chemistry and Biochemistry at the University of California, Merced. Her primary research area is resonance Raman spectroscopy, linear and nonlinear, but she has also worked in several other areas of spectroscopy including single-molecule and line-narrowed fluorescence, four-wave mixing, and time-resolved methods.

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